The changes in macromineral (Ca, P, Mg, K, Na, Cl and S) and micromineral (Cu, Fe,
Mn, Zn, Co and Se) concentrations in herbage were followed during the harvesting
and conservation processes of barn‐ and field‐dried hay and silage. In total, 131 herbage
samples originating from 50 harvests were collected in fresh form before
mowing, in wilted form at harvest and in conserved form after storage. During the
harvesting process, initial Ca, Mg and Zn concentrations in herbage decreased by 7–
17% for barn‐dried hay, and initial Ca concentration decreased by 7% in herbage for
silage (explained by losses of mineral‐rich and fragile plants or plant parts during the
mechanical treatments). During the conservation process, mineral concentrations
remained stable in barn‐dried hay, but macro‐ and micromineral concentrations
increased on average by 6% and 31%, respectively, in silage (explained by loss of
fermentable nutrients). Overall, in conserved hay (field‐ and barn‐dried hay), concentrations
were decreased as follows: Ca 25%, Mg 15%, Cu 9% and Zn 12%; and in
silage, concentrations increased as follows: Mg 12%, Na 33%, Mn 65%, Zn 13% and
Se 27%, relative to the initial fresh form. During the harvesting process, ash, Fe and
Co concentrations increased by factors of 0.29, 7.6 and 8.8 in wilted herbage for
silage. Iron and Co concentrations in wilted and conserved herbage were linearly
correlated with increasing ash concentration from a breakpoint of 100 g/kg dry matter,
indicative of increasing soil contamination.